About 4,000 union miners have been laid off from Pittston operations.
Other union miners were likewise ordered to draw their pay and leave.
The violence committed by union miners was answered with a brutal response in 1892 and in 1899.
Many union miners view the mountain as a shrine to their movement's struggles.
Under the terms of the settlement, the 82 union miners will each receive $38,000.
Thousands attended the funerals of the two union miners who died during the siege.
Alabama's 5,000 union miners planned to return to work Sunday night, said a union official there.
The union miners fired into a remaining structure where the guards had taken shelter.
Fifty union miners left the scene to cross the street to the union hall.
At least four union miners and one fireman were killed.