phenolate

It can be prepared from sodium phenolate and carbon dioxide under higher temperature and pressure.

However, as phenols, they form more water-soluble phenolate salts under strongly alkaline conditions.

The British P gas helmet, issued at the time, was impregnated with sodium phenolate and partially effective against phosgene.

The Kolbe-Schmitt reaction proceeds via the nucleophile addition of a phenolate to carbon dioxide to give the salicylate.

The cyclic intermediate is opened up to form a more stable phenolate, which is protonated during acidic work-up to give the desired product.

Phenolate (Zinc oxide-eugenol and EBA)

It had flannel layers of cloth-dipped in sodium phenolate and glycerin and protected against chlorine and phosgene, but not against tear gas.

A reaction mechanism has been postulated accounting for the observed para substitution featuring the tautomeric para carbanion of the starting phenolate ion:

In this case, DMAP acts as a base and deprotonates the phenol, and the resulting phenolate ion adds to the anhydride.

The reactivity of the iron center may be improved by the presence of the phenolate ligand of Tyr357 in the fifth iron ligand, which can assist in the oxidation of the Fe(III) to Fe(IV).