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It can be prepared from sodium phenolate and carbon dioxide under higher temperature and pressure.
The British P gas helmet, issued at the time, was impregnated with sodium phenolate and partially effective against phosgene.
Like other sodium alkoxides, crystalline sodium phenolate adopts a complex structures involving multiple Na-O bonds.
It had flannel layers of cloth-dipped in sodium phenolate and glycerin and protected against chlorine and phosgene, but not against tear gas.
Triazenes of type 2 are also formed by reaction of the acetoxymethyltriazene with the sodium phenolate, generated by reaction of the phenol with sodium hydride in dry chloroform, but under these conditions a second product is formed, which has been identified as an isomer of 2.