She was defeated in straight sets with a score of 21-11 and 22-20.
He was defeated in three straight sets 4-6, 7-6 and 6-4.
They were defeated by the Williams in two sets, 6-3, 6-3.
After taking the first set in a tiebreak, Murray was eventually defeated in four sets.
Nadal failed to win his 9th title after Djokovic defeated him in straight sets 6-2, 7-6.
The quarterfinals saw the end of Martin, being defeated by Kafelnikov in three sets.
Sharapova then defeated Karatantcheva in three sets in the third round.
She then defeated Williams in straight sets during an exhibition in Toronto.
Kristina Barrois defeated her in the second round in straight sets.
She defeated the defending champion Li Na in three sets.