"interaction" nach Englisch mit Beispielen - Kollokationen-Wörterbuch Englisch
- The reason is the unfavorable steric interactions of ethylenedioxy analogues with the enzyme.
- An example is 1,2,4,5-tetrathiane, an organosulfur compound where four of the methylene bridges are replaced by a sulfide group (thus removing unfavorable 1,3-diaxial interactions).
- On the contrary, when the electrophile attacks from the bottom face, such unfavorable interaction does not exist.
- These inverse micelles are proportionally less likely to form on increasing headgroup charge, since hydrophilic sequestration would create highly unfavorable electrostatic interactions.
- A hypersensitivity to pregabalin or another component of the product may develop, resulting in an unfavorable interaction with the body.
- The most energetically unfavorable interaction involves axial substitution at the vertex of the boat portion of the ring (6.1 kcal/mol).
- Purines are too large to fit in the active site, while unfavorable interactions with other pyrimidines discourage binding alternative substrates.
- An ion can associate diffusely with the RNA backbone, shielding otherwise unfavorable electrostatic interactions.
- The β-trans-axial substituent influences the transition state by also causing an unfavorable steric interaction between the two groups.
- In the example below, the silyl-group acts to direct the cyclization by preventing the distant alkene from rotating "towards" it via unfavorable steric interaction.
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