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It is commonly believed that in HILIC, the mobile phase forms a water-rich layer on the surface of the polar stationary phase vs. the water-deficient mobile phase, creating a liquid/liquid extraction system.
The aqueous solution as a dense medium is used in coal processing in the form of a belknap wash and the suspension in air is used in water-deficient areas, like china, where sand is used to separate coal from the gangue minerals.
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