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Each is directly related to a second order differential of a thermodynamic potential.
Any of the thermodynamic potentials may be held constant during a process.
The energy needed can be expressed as an excess thermodynamic potential of the water in the solution.
As in the above sections, this process can be carried out on all of the other thermodynamic potentials.
As an example of another thermodynamic potential, the Helmholtz free energy is written:
Thermodynamic potentials are different quantitative measures of the stored energy in a system.
A typical application is the calculation of a thermodynamic potential from a partition function.
Their order is determined by the first discontinuous derivative of a thermodynamic potential.
In order to understand the value of the thermodynamic potentials, it is necessary to view them in a different light.
Other thermodynamic potentials can also be obtained through Legendre transformation.
The relevant thermodynamic potential is the free energy (or the free entropy).
Similar equations can be developed for all of the other thermodynamic potentials of the system.
The basic thermodynamic potential is internal energy.
These state functions are known as thermodynamic potentials.
The differences between the four thermodynamic potentials can be summarized as follows:
The most important thermodynamic potentials are the following functions:
Specifically, they split most of the thermodynamic potentials into classical and electrostatic terms.
For the most simple case, a single phase ideal gas, there will be three dimensions, yielding eight thermodynamic potentials.
Second derivatives of thermodynamic potentials generally describe the response of the system to small changes.
In addition to and , the other thermodynamic potentials are frequently used to determine exergy.
In fact, all thermodynamic potentials are expressed in terms of conjugate pairs.
If Φ is a thermodynamic potential, then the fundamental equation may be expressed as:
Specifically, thermodynamic equilibrium is characterized by the minimum of a thermodynamic potential.
A thermodynamic potential is a scalar quantity used to represent the thermodynamic state of a system.
The concept of thermodynamic potentials was introduced by Pierre Duhem in 1886.