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A number of primary and secondary alcohols was tested, from methanol to 2-butanol.
Secondary alcohols react faster than primary ones, although selectivity is low.
Less often, they are produced from secondary alcohols.
Secondary alcohols react within five or so minutes (depending on their solubility).
Secondary alcohols are converted into ketones - no further oxidation is possible.
The reagent is mainly used for the synthesis of chiral secondary alcohols.
This is also the case when testing for secondary alcohols (methyl alcohols).
DCC can also be used to invert secondary alcohols.
The resulting catalyst was then successfully used for the chemoselective oxidation of primary and secondary alcohols.
On oxidation the secondary alcohols form ketones.
Jones reagent interacts with secondary alcohols resulting in oxidation to ketones.
Secondary alcohols oxidise to form alkanals (aldehydes) and then alkanoic acids.
If primary or secondary alcohols are to be reacted with hydrochloric acid, an activator such as zinc chloride is needed.
The oxidation of secondary alcohols to ketones is an important oxidation reaction in organic chemistry.
RuO readily converts secondary alcohols into ketones.
For specialized or small scale organic synthetic applications, ketones are often prepared by oxidation of secondary alcohols:
Treatment of compounds, containing both primary and secondary alcohols, with Jones reagent leads to formation of ketoacids.
Jones reagent will convert primary and secondary alcohols to aldehydes and ketones, respectively.
Phosphorus triiodide is commonly used in the laboratory for the conversion of primary or secondary alcohols to alkyl iodides.
Under those conditions yields of 87-98% of primary and secondary alcohols were oxidized to aldehydes and ketones.
The main use for phosphorus tribromide is for conversion of primary or secondary alcohols to alkyl bromides, as described above.
Because of the S2 substitution step, the reaction generally works well for primary and secondary alcohols, but fails for tertiary alcohols.
Some can also oxidize select diols, secondary alcohols, hydroxy fatty acids, and even long-chain aldehydes.
Swern oxidation oxidises secondary alcohols into ketones using oxalyl chloride and dimethylsulfoxide.
Secondary alcohols can be stereochemically inverted by formation of a formyl ester followed by saponification.