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The reduction does not follow second-order reaction kinetics.
The algebra of systems of second-order reactions.
Draw and analyse graphical representations for zero-, first- and second-order reactions.
Decomposition of reagents is bimolecular (second-order reaction rate), so low amounts of oxone and catalyst are used.
The reaction of methyl acetate and a base, for example sodium hydroxide, is a second-order reaction with respect to both reactants.
The rate of a second-order reaction may be proportional to one concentration squared , or (more commonly) to the product of two concentrations .
With excess amine, pseudo-first-order rate constants for the production of 2 were measured, which showed a second-order reaction, together with a catalysed third-order reaction.
This is an example of an esterification reaction where one molecule acetic acid reacts with one molecule ethanol, yielding one molecule ethyl acetate (a bimolecular second-order reaction of the type A + B C):
When the reaction was monitored using an absorption band at 385 nm it was possible to detect two processes; the first, a rapid second-order reaction which yielded a ruthenium(VI) moiety, was followed by a much slower first-order decomposition of this intermediate.
Kinetic studies have shown that the association of [3H]corticosterone–receptor followed second-order reaction kinetics and the dissociation of the ligand from the receptor became "pseudo" first order in the presence of large excess of radioinert steroids at 0, 15, 25, and 35 °C.
The kinetics of both the β β-sultone formation and the direct hydrolysis shows two terms, one first order in 1 alone, and the other first order in hydroxide as well; the rates of the first- and second-order reactions are lowered by added sodium chloride.