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Such bonds usually only participate in radical substitution.
Another important class of radical substitutions involve aryl radicals.
Coupling reactions can also be considered radical substitutions.
Free radicals also take part in radical addition and radical substitution as reactive intermediates.
This deoxygenation reaction is a radical substitution.
These reactions can be distinguished by the type of substituting species into a nucleophilic, electrophilic or radical substitution.
A radical substitution reaction involves radicals.
In the third type of substitution reaction, radical substitution, the attacking particle is a radical.
The other radical reactions: radical substitution and radical polymerization.
It is a radical substitution to an aromatic compound, in particular to a heteroaromatic base, that introduces an alkyl group.
More radical substitutions are listed below:
In a free radical substitution reaction, if the formation of the free radical takes place at a chiral carbon, then racemization is almost always observed.
In free radical halogenation reactions radical substitution takes place with halogen reagents and alkane substrates.
Bromocyclohexane can be prepared by the free radical substitution of bromine to the cyclohexane ring at high temperatures or in presence of electromagnetic radiation.
In this radical substitution the aryl halide 1 accepts an electron from an radical initiator forming a radical anion 2.
N-Bromosuccinimide or NBS is a chemical reagent used in radical substitution and electrophilic addition reactions in organic chemistry.
In the Barton-McCombie deoxygenation an alcohol is deoxygenated to an alkane with tributyltin hydride or a trimethylborane-water complex in a radical substitution reaction.
In this particular "intramolecular KIE" study the radical substitution of hydrogen by bromine is examined in the reaction involving N-bromosuccinimide as the brominating agent.
Fenton's reagent is also used in organic synthesis for the hydroxylation of arenes in a radical substitution reaction such as the classical conversion of benzene into phenol.
This finding is in accordance with the general accepted view of a radical substitution in which a hydrogen atom is removed by a bromine free radical species in the rate-determining step.