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In some cases, an alternative to traditional potentiometric titration practice can be offered.
Automated potentiometric titration systems have pre-dominated in this area since the 1970s.
Figure 3 gives sample plots of potentiometric titration data.
Log β values between about 2 and 11 can be measured directly by potentiometric titration using a glass electrode.
Thus the potentiometric titration involve measurement of E with the addition of titrant.
Potentiometric titration is a technique similar to direct titration of a redox reaction.
Quantitative analysis of hydroperoxides is performed using potentiometric titration with lithium aluminium hydride.
The end of process is determined by potentiometric titration in a manner similar to Karl Fischer titration.
The calculation of hydrogen ion concentrations, using this formalism, is a key element in the determination of equilibrium constants by potentiometric titration.
Similarly, the potentiometric titration of sulfate with barium chloride in various industrial samples can lead to rapid degradation of the indicating barium ion selective electrode.
Potentiometric titration: The sample is normally dissolved in toluene and propanol with a little water and titrated with alcoholic potassium hydroxide (if sample is acidic).
Automated potentiometric titration procedures have been granted standard method status, for example by ASTM for TAN and AOAC for FFA.
A Gran plot (also known as Gran titration or the Gran method) is a common means of standardizing a titrate or titrant by estimating the equivalence volume or end point in a strong acid-strong base titration or in a potentiometric titration.