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Its reaction products are oligonucleotides or single nucleotides with 5' phosphoryl groups.
The largest functional group is related to phosphoryl transfer and protein kinases.
And, this is sufficient to support an associative reaction mechanism for phosphoryl transfer.
Interestingly, many of the biological functions involving phosphoryl transfer form large gene clusters as well.
The lactam is first treated with phosphoryl chloride to produce a dibenzothiazepine.
This page provides supplementary chemical data on phosphoryl chloride.
Phosphoryl fluoride (commonly called phosphorus oxyfluoride) is a toxic gas.
By convention, the phosphoryl group that is transferred is referred to as a phosphate group.
Characterization and evidence for ping pong kinetics involving phosphoryl enzyme.
Another synthesis is to chlorinate pyridinol with phosphoryl chloride.
Like phosphate, phosphoryl chloride is tetrahedral in shape.
Phosphoryl chloride (POCl) is widely used and cited for this purpose.
The initial phosphoryl transfer takes place from the phosphoserine to the substrate, creating a bisphosphorylated sugar intermediate.
His seems to enhance the binding of the substrate's phosphoryl group and orient adenylosuccinate for catalysis.
In sphingomyelin the primary hydroxyl group of sphingosine is esterified to phosphoryl choline.
The reaction involves two separate phosphoryl groups and the ending phosphate on the 2-carbon is not the same phosphate removed from the 3-carbon.
The phosphoryl group on PEP is eventually transferred to the imported sugar via several proteins.
The mechanism by which this phosphoryl transfer reaction is catalyzed is an area of ongoing research, though several extreme possibilities exist.
Phosphoryl nitride in chemistry is a reactive intermediate with the structure OPN.
Next, the phosphoryl group on G6P can be cleaved by glucose-6-phosphatase so that a free glucose can be formed.
These proteins contain a pseudo-substrate sequence thought to interfere with Jak substrate binding and phosphoryl transfer.
The most important chemical reactions of phosphoryl halides is the hydrolysis of the bond between phosphorus and the fluoride.
This is followed by a second phosphoryl transfer from the substrate back to enzyme, producing product and regenerating the active form of the enzyme.
The response regulator CheB takes the phosphoryl group from CheA].
Phosphoryl chloride can be prepared by the reaction of phosphorus trichloride with oxygen at 20-50 C (air is ineffective):