mononuclear complex

The mononuclear complexes in water generate aquo and hydroxo species.

O can bind to one metal of a bimetallic unit via the same modes discussed above for mononuclear complexes.

In photocatalysis, the use of mononuclear complexes is usually limited either because they only undergo single- electron process or from the need for high-energy irradiation.

In mononuclear complexes with large m and n, the rings will rotate to reduce torsional strain within the linker arms.

Copper(II) forms mononuclear complexes that are paramagnetic and prefers ligands of sulfur and nitrogen.

Except vanadium hexacarbonyl only metals with even order number such as chromium, iron, nickel and their homologs build neutral mononuclear complexes.

The mononuclear complexes (I) exist in two isomeric forms differing in the coordination of monodentate acetamidine ligand.

Mononuclear complexes feature terminal nitride ligands, typically with short M-N distances consistent with metal ligand multiple bonds.

The mononuclear complexes, involving protonated ligand, result from the sensitivity of these ligands to mildly acidic conditions in aqueous solutions of certain copper salts.

Compound 1 is a mononuclear complex with the aluminum atom in an approximately trigonal bipyramidal geometry and the amido nitrogen atom in a trigonal planar geometry.

The reaction of PMe3 with these clusters results in the formation of mononuclear complexes of the formula HRh(PMe3)2(R2PCH2CH2PR2).