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In practice a molar equivalent of PBr is often used anyway to overcome the slow reaction kinetics.
Molar equivalents of transposon and target plasmid (0.4 fmoles ea.)
The products formed were identified by paper chromatography, isolation, and n.m.r. spectroscopy. In all cases less than one molar equivalent of tetronic acid is produced.
If an aqueous solution is desirable, a full molar equivalent of PBr must be used as the catalytic chain is disrupted.
The reaction is initiated by addition of a catalytic amount of PBr, after which one molar equivalent of Br is added.
Disodium glutamate can be produced by neutralizing glutamic acid with two molar equivalents of sodium hydroxide (NaOH).
With one molar equivalent of anhydrous HCl, the simple addition product 6a can be formed at low temperature in the presence of ether, but it is very unstable.
Reaction of the ionic liquid layer with two molar equivalents of water gives the crystalline product (HO)[HO 18-crown-6]Cl.
Hydrofuramide is a condensation product of three molar equivalents of furfural with two molar equivalents of ammonia.
The presence of trifluoroacetic acid during this oxidation process led to varying degrees of epimerization about phosphorus and was dependent on the relative molar equivalents of this acid.
In this reaction, a catalytic amount of organic peroxide is needed to abstract the acidic proton from HBr and generate the bromine radical, however a full molar equivalent of alkene and acid is required for completion.
When PO is reacted with one molar equivalent of (CH)S-BH, followed by slow crystallization from the toluene solution at 244K, PO(BH) rather than an adduct of PO is formed:
Barbitone was prepared by condensing diethylmalonic ester with urea in the presence of sodium ethoxide, and then by adding at least two molar equivalents of ethyl iodide to the silver salt of malonylurea or possibly to a basic solution of the acid.
Glutathione reductase functions as dimeric disulfide oxidoreductase and utilizes an FAD prosthetic group and NADPH to reduce one molar equivalent of GSSG to two molar equivalents of GSH:
Draw only the structure of the major product of the reaction of one molar equivalent of bromoethane with: a) G plus two molar equivalents of base b) G plus one molar equivalent of base v) A side reaction of G is its oxidative dimerization.