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He also contributed to the development of so-called "living polymerization".
He also produced some important work on "living polymerization".
Living polymerization was demonstrated by Szwarc and co workers in 1956.
He focused on solving practical problems associated with the living polymerization techniques in the industry.
Starting in the 1970s several new methods were discovered which allowed the development of living polymerization using free radical chemistry.
The reaction is believed to be a living polymerization due to the lack of competing reactions.
This technique is also known as living polymerization.
Ideal living polymerization results in a polydispersity of 1.
Living polymerization, however, produces only one type of tacticity per catalyst.
Twenty years later, living polymerization was demonstrated by Szwarc.
Under the necessary reaction conditions, an addition polymerization can be considered a living polymerization.
Living polymerization, a special case of addition polymerization, leads to values very close to 1.
A special case of chain-growth polymerization leads to living polymerization.
All polymers resulting from living polymerization are end-functional but may not necessarily be telechelic.
Being a physical chemist, Szwarc set forth in understanding the mechanism of such living polymerization in greater detail.
The main living polymerization techniques are:
A cascade reaction is sometimes called a living reaction because it shares some characteristics with a living polymerization.
The following experimental criteria have been proposed as a tool for identifying a system as living polymerization system.
The material was made by living polymerization so that the blocks are almost monodisperse, so helping to create a very regular microstructure.
Group-transfer polymerization also has characteristics of living polymerization.
In this case, the polymerization is considered to be a living polymerization because propagation can continue if more monomer is added to the reaction.
Living polymerization in the literature is often called "living" polymerization or controlled polymerization.
An analogous equation can be written for living polymerization, a type of addition polymerization, and is usually written as:
Living polymerization is a popular method for synthesizing block copolymers since the polymer can be synthesized in stages, each stage containing a different monomer.
The high ratio of the rate of initiation to the rate of propagation makes these catalysts useful in living polymerization.