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He also recognized the opportunities of measuring the limiting currents.
E1/2 can be used to identify the unknown species while the height of the limiting current can determine the concentration.
The limiting current can be approached, for example, by increasing the electric potential or decreasing the rate of mass transfer to the electrode.
The results showed that, the total limiting current of each of the studied compounds corresponds to 2-electron transfer process.
The form of the solution is shown to depend on whether or not the interrupted current was close to the limiting current of the reduction.
The below chart displays the temperature limiting currents and SCL effects.
The results were analysed by determining Koutecky's parameter from the ratio of the limiting current of the prewaves and the main wave.
Polarographic limiting currents were well-defined, so that the bulk concentration of reactant during reduction could be clearly followed as a function of time.
"Limiting currents in potentiostatic voltammetry without supporting electrolyte," Electrochemistry Communications, Vol.1, 1999, pp.467-471.
The diffusion coefficient of prodan was determined from both limiting currents from convoluted cyclic voltammograms as well as limiting currents on ultramicroelectrodes.
The limiting current is typically much higher than the peak current of a stationary electrode, being that the mass transport of reactants is actively stimulated by the rotating disk, and not just governed by diffusion, as is the case for a stationary electrode.