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Hydrosilylation has been called the "most important application of platinum in homogeneous catalysis."
These compounds can undergo hydrosilylation reactions to form dendrimers.
Aldehydes undergo hydrosilylation in the presence of hydrosilanes and fluoride.
Optimal yields of the hydrosilylation are obtained when the reaction is carried out in very polar solvents.
Hydrosilylation may be used to reduce ketones after silyl ether hydrolysis.
This reaction is reported as being selective for only the dehydrogenative coupling and not the hydrosilylation reaction.
The reaction is called hydrosilylation.
Via hydrosilylation, trichlorosilane is a precursor to other useful organosilicon compounds:
Important examples include hydrogenation, hydroformylation, hydrosilylation, hydrodesulfurization catalysts.
Comprehensive handbook on hydrosilylation.
Examples are hydroboration, hydrosilylation and hydrozirconation.
This reaction type can be extended to compounds of silicon bonded to a suitable metal in so-called silylmetalation as an extension to hydrosilylation.
Chloroplatinic acid (HPtCl) is an important catalyst for hydrosilylation.
Rhodium complexes as hydrosilylation catalysts.
As an example, compound 1 was synthesized by a divergent approach in which tetraallylsilane undergoes Pt-catalyzed hydrosilylation to form the core.
Another common reaction is hydrosilylation, which dates back to the first use of PyBOX ligands.
Many kinds of organic compounds with various functions can be introduced onto the silicon surface by the hydrosilylation of a hydrogen-terminated surface.
Hydrosilylation, also called catalytic hydrosilation, describes the addition of Si-H bonds across unsaturated bonds.
Compounds with Si-H bonds add to unsaturated substrates in the process called hydrosilylation (also called hydrosilation).
As an example, decaallylferrocene (3) can undergo hydrosilylation with dimethylferrocenylsilane to form a decaferrocenyl functionalized ferrocene as is shown in figure 2.
Rhodium(I) and rhodium(III) salts are the most common catalysts for hydrosilylation.
Fe(DIP)(N) is a precursor to highly active catalysts for hydrosilylation and hydrogenation reactions.
Complexes of DIPs participate in a range of chemical reactions, including ethylene polymerization, hydrosilylation, and hydrogenation.
Complexes derived from noncoordinating anions have been used to catalyze hydrogenation, hydrosilylation, oligomerization, and the living polymerization of olefins.
Silyl hydrides react with various unsaturated substrates such as alkenes, alkynes, imines, carbonyls and oximes to new organosilicon compounds in hydrosilylation.