homogeneous reaction

The mechanism is discussed, and an upper limit is determined for the rate constant of the homogeneous reaction.

Homogeneous reactions with metal coordination complexes proceed somewhat faster.

It was observed that a homogeneous reaction medium proved beneficial for the yield of the reaction.

The standard MPV reduction is a homogeneous reaction several heterogeneous reactions have been developed.

In organic chemistry, on water reactions are the exception to the rule that homogeneous reactions take place faster than heterogeneous reactions.

Hong C. Shen summarized homogeneous reactions forming cyclic compounds into 4 main categories:

The electron-donating nature as well as the hydrophobic characteristics of the methyl group influence the kinetics of the homogeneous reaction.

The epoxidation can take place either in a homogeneous reaction by peracids or heterogeneous catalysis (e.g. silver and molecular oxygen).

Utilization of this catalyst in homogeneous reaction conditions enabled marked extension of the methodology to α,β-unsaturated ketones, dienes, and bis-dienes.

The theory of the catalytic regeneration mechanism involving an electrode reaction followed by a coupled chemical reaction is applied to derive kinetic parameters of homogeneous reaction.

Homogeneous reactions are chemical reactions in which the reactants and products are in the same phase, while heterogeneous reactions have reactants in two or more phases.

Until the 3rd day, a homogeneous reaction is registered for the whole of the two first internodes. Three maxima of mitotic activity are detected in the epidermis, the cortex, and the procambium and only one in the pith.

Direct, independent heating of the substrate was employed; this configuration limits the undesirable homogeneous reaction, effectively the reactor is somewhat akin to a chemical vapour deposition (CVD) reactor with cold walls and a heated substrate.

It also was shown that the rates of the electrochemical reactions were generally slower than those of homogeneous reactions in which a stoichiometric amount of benzoquinone was used, indicating that the electrochemical regeneration of benzoquinone was mass transport limited at the highest concentrations of perchloric acid.