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These two cytochromes are considered high-spin complexes, what is directly related to the electrons' spin.
It is configurationationally labile, high-spin complex with five unpaired electrons.
The spin-only formula is a good first approximation for high-spin complexes of first-row transition metals.
Ferric acetylacetonate, Fe(acac), is a red high-spin complex that is highly soluble in organic solvents.
It is now known that the iron(II) in hemoglobin is a low-spin complex, whereas in oxyhemoglobin it is a high-spin complex.
An example occurs in octahedral, high-spin complexes of manganese(II), which has a d configuration in which all five electron has parallel spins; the colour of such complexes is much weaker than in complexes with spin-allowed transitions.