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Their properties have been studied by ligand substitution and complex formation reactions.
In the present communication the method for account of this effect in mixed fluids on the complexes formation reactions is proposed.
A considerable enhancement of the rate of ionization of the enol tautomers of these ligands was observed during the complex formation reactions with Cu2+.
However, solvation resembles a coordination complex formation reaction, often with considerable energetics (heat of solvation and entropy of solvation) and is thus far from a neutral process.
Kinetics of the complex formation reaction between aquo iron(III) species and glutathione are slower than rates of reaction of iron(III) with simple ligands.
The reactions display the apparent "anomaly" in the direction of slow reaction reported earlier for some other complex formation reactions of Ni(DMSO)62+ in DMSO.