Weitere Beispiele werden automatisch zu den Stichwörtern zugeordnet - wir garantieren ihre Korrektheit nicht.
An unexpected compound, 3-benzoyl-2-methylcyclohexanol, was isolated from the reaction of 1-methylcyclohexene with benzoyl chloride.
For benzoyl chloride, the partial hydrolysis of benzotrichloride is useful:
Benzoyl chloride is produced from benzotrichloride using either water or benzoic acid:
An early method for production of benzoyl chloride involved chlorination of benzyl alcohol.
Oxybenzone is produced by Friedel-Crafts reaction of benzoyl chloride with 3-methoxyphenol(3-hydroxyanisole).
A double ring-expansion reaction is observed with benzoyl chloride as with simple phospholes.
It is possible to use benzoyl chloride but the yields and regioselectivity of the addition of the cyano group are lower.
An example, published in 1924, illustrates the reaction in a substituted benzoyl chloride system:
Benzoyl chloride is a typical acyl chloride.
A 2% crosslinked divinylbenzene–styrene copolymer, incorporating benzoyl chloride groups, was used to monoprotect the symmetrical diol 1,10-decanediol.
The acylation of 1-methylcyclohexene with propionyl, butyryl, and benzoyl chloride in the presence of different Lewis acids is reported.
One experiment published in 1862 described the first nucleophilic displacement of chlorine by fluorine in benzoyl chloride.
It was prepared by treating benzoyl chloride with barium peroxide, a reaction that probably follows this equation:
Benzotrichloride is hydrolysed to benzoyl chloride:
The amine group was benzoylated with benzoyl chloride (61) and hydrolysis removes the thioether group in 62.
The strained ring benzocyclobutenone has been prepared by FVP from a simple benzoyl chloride precursor.
Benzoyl peroxide is usually prepared by treating hydrogen peroxide with benzoyl chloride.
In one reported oxazole synthesis the reactants are a nitro-substituted benzoyl chloride and an isonitrile:
If benzoic anhydride (or benzoyl chloride) is used, a particular type of chromone called a flavone is obtained.
A partial extraction procedure was developed in 1935 which involved reacting the compound with benzoyl chloride to allow it to be separated from the water-soluble components.
One example is the conversion of benzoyl chloride with sodium peroxide to di benzoyl peroxide.
A modern synthesis of hippuric acid involves the acylation of glycine with benzoyl chloride:
Most often R is acetyl or benzoyl, with acetic anhydride or benzoyl chloride used in the preparation of 2.
In 1857 Hugo Schiff observed that the reaction between benzoyl chloride with potassium cyanide produced the desired benzonitrile.
Friedel-Crafts acylation of the n-butyl ether of thiophenol with benzoyl chloride gives the corresponding benzophenone.