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Antibonding molecular orbitals (MOs) are normally higher in energy than bonding MOs.
The bond order, or number of bonds, of a molecule can be determined by combining the number of electrons in bonding and antibonding molecular orbitals.
Also, the high resolution allowed the observation of fine structure due to vibrational levels of the molecular ion, which facilitates the assignment of peaks to bonding, nonbonding or antibonding molecular orbitals.
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