anisole

These steps are outlined below for the case of anisole.

The title compound crystallizes from anisole with 4 molecules per unit cell.

For example, synthetic anethole is prepared from anisole.

A wide variety of phenols undergo O-methylation to give anisole derivatives.

It is also readily prepared from anisole and propionic acid via the intermediacy of 4-methoxypropiophenone.

Some inconclusive dynamic nmr experiments on anisole, including T1ρ measurements, are briefly discussed.

The reduction of anisole is one of the simplest examples and is shown in equation 1.

Deblocking with aluminium chloride and anisole gives moxalactam 14.

While phase and solvent effects on the internal barrier in anisole are certainly substantial, it appears that a fourfold component must also be present.

Taylor Reaction between N-bromosuccinimide and anisole in aqueous solution (1947)

Other methoxy ethers include anisole and vanillin.

Some apples carry anise-flavored anisole.

In common with anisole the reaction of ferrocene with P4S10 forms a dithiadiphosphetane disulfide.

One example involves anisole:

Illustrative of its nucleophilicity, anisole reacts with acetic anhydride to give 4-methoxyacetophenone:

So it attracts them by releasing anisole and veratrole, two insect pheromones, when the truffle has reached maturity.

Molecular orbital computations with the basis set 6-31G are reported for seven values of θ, the torsion angle about the bond in anisole.

It has an anisole (methoxybenzene) core, with two nitro groups (-NO) attached.

The photoreaction of caffeine with dioxane, tetrahydrofuran, tetrahydropyran, anisole, and ethyl ether has been studied.

The consortium O-demethylated anisole to phenol and 2-methoxyphenol to catechol, and oxidized 2-hydroxybenzyl alcohol to 2-hydroxybenzoic acid.

For instance anisole with lead tetraacetate forms 'p-methoxyphenyllead triacetate in chloroform and dichloroacetic acid:

In the presence of added methanol either phenol or anisole give 47–63% of methylbenzenes and 22% of methylated phenols.

The different mechanism is followed in order to avoid the fully protonated hemiacetal, which, being of an O-protonated anisole structure, is of very high energy.

The rate of dissociation of anisole into phenoxy and methyl radicals has been measured using a toluene scavenging technique.

The enhanced nucleophilicity of anisole vs benzene reflects the influence of the methoxy group, which renders the ring more electron-rich.