aldol reaction

These first two steps are similar to a base-catalyzed aldol reaction.

The aldol reaction may proceed via two fundamentally different mechanisms.

The aldol reaction is a very important reaction in organic chemistry.

The aldol reaction is powerful because it unites two relatively simple molecules into a more complex one.

As for carbon compounds, catalysed Michael additions and aldol reactions can be used.

This is the first example of an amino acid-catalyzed asymmetric aldol reaction.

This enolate was reacted with 4-pentenal in an aldol reaction to give β-hydroxyketone 9.

Modern ways of doing the aldol reaction also allow to control the stereochemistry of the product.

The best example is the aldol reaction.

Carbonyls also may be alkylated by enolates as in aldol reactions.

He has also developed novel methodology for organic synthesis such as a modification of the Evans aldol reaction.

The scheme shows a simple mechanism for the base-catalyzed aldol reaction of an aldehyde with itself.

Thus, they described the first use of proline in a catalytic asymmetric aldol reaction.

Highly enantioselective reactions have been discovered in this manner such as the aldol reaction depicted below.

The aldol reaction is particularly useful because two new stereogenic centers are generated in one reaction.

The amide tail synthesis (scheme 7) was based on an asymmetric Aldol reaction.

There is another aspect of aldol reaction that is influenced by the allylic strain.

They can also do aldol reactions.

Chiral oxazolidinones have been employed most widely in stereoselective aldol reactions.

The Mukaiyama aldol reaction does not follow the Zimmerman-Traxler model.

The acidity of carbonyl compounds is an important driving force in many organic reactions such as the aldol reaction.

On the second aldol reaction, the product which is a 1,3 dicarbonyl is formed in high diastereoselectivity.

In the second mechanism the first step is Schiff base formation to 5 followed by Aldol reaction to 6 and elimination to 7.

The number of reactions hinting at the actual process taking place is much smaller, for example the ene reaction or aldol reaction.

In 1872 he discovered the aldol reaction and characterized the product as showing the properties of both an alcohol and an aldehyde.