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A yellow precipitate of the metal acetylide is formed in this case.
Thus it reacts with strong bases to form acetylide salts.
Silver acetylide can be obtained in a similar way from silver nitrate.
This is the same synthesis from Berthelot in which he first found silver acetylide in 1866.
The azide and the acetylide are not coordinated to the same Cu atom in this case.
The acetylide, Al(C), is made by passing acetylene over heated aluminium.
Hence, the bonding in compounds like sodium acetylide and triphenylmethylpotassium is primarily ionic.
Some acetylides (chemical compounds contain acetylide ions) are explosive.
The metal acetylide then reacts with an aldehyde or ketone to form a propargyl alcohol.
I broke open the liquid-oxygen compartments and when the spark went through the acetylide mixture the whole cursed thing exploded."
Silver acetylide is not soluble in water and there are no known solvents for it other than those that would decompose it.
Copper acetylide is the substrate of Glaser's reaction for the formation of polyynes.
It also contains acetylide ions.
I. Mercuric acetylide.
Copper(I) acetylide is an example.
Copper(I) acetylide is a reddish solid.
Pure silver acetylide is a heat- and shock-sensitive high explosive with the unusual property that on ignition it does not evolve any gas:
Silver acetylide can be produced by passing acetylene gas through a solution of silver nitrate:
It explodes because the acetylide is a reducing agent and the copper(I) is an oxidizing agent.
It is similar to silver acetylide and calcium carbide, though it is not called carbide in literature.
Copper acetylide can form inside pipes made of copper or an alloy with high copper content, which may result in violent explosion.
Copper(I) acetylide, also known as cuprous acetylide, is a chemical compound.
The acetylide conjugate base to be stabilized as a result of the high s character of the sp orbital, in which the electron pair resides.
Similarly, silver nitrate is used to prepare some silver-based explosives, such as the fulminate, azide, or acetylide, through a precipitation reaction.
Metals from group 11 also tend to form acetylides, such as copper(I) acetylide and silver acetylide.